Film formation from nano-sized polystyrene latex particles

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dc.authorid0000-0003-2876-470X
dc.authorid0000-0002-2151-9894
dc.authorid0000-0002-0082-8209
dc.contributor.authorUğur, Şaziyeen_US
dc.contributor.authorElaissari, Abdelhamiden_US
dc.contributor.authorPekcan, Mehmet Önderen_US
dc.date.accessioned2015-01-15T23:00:20Z
dc.date.available2015-01-15T23:00:20Z
dc.date.issued2005-05
dc.departmentIşık Üniversitesi, Fen Edebiyat Fakültesi, Fizik Bölümüen_US
dc.departmentIşık University, Faculty of Arts and Sciences, Department of Physicsen_US
dc.description.abstractThis work reports on the steady state fluorescence (SSF) technique for studying film formation from surfactant-free, nano-sized polystyrene (PS) latex particles prepared via emulsion polymerization. The latex films were prepared from pyrene M-labeled PS particles at room temperature and annealed at elevated temperatures in 5, 10, 15, 20 and 30 min time intervals above the glass transition temperature (T-g) of PS. During the annealing processes, the transparency of the film was improved considerably. Monomer and excimer fluorescence intensities, I-p and I-E respectively, from P were measured after each annealing step to monitor the stages of film formation. Evolution of transparency of the latex films was monitored by using photon transmission intensity, It,. Void closure and interdiffusion stages were modeled and related activation energies were determined and found to be 10.3 and 50.3 kJ mol(-1). Void closure temperatures, T-v, were determined from the minima of I-tr value. Copyrighten_US
dc.description.versionPublisher's Versionen_US
dc.identifier.citationUğur, Ş., Elaissari, A. & Pekcan, M. Ö. (2005). Film formation from nano‐sized polystyrene latex particles. Polymers for Advanced Technologies, 16(5), 405-412. doi:10.1002/pat.597en_US
dc.identifier.doi10.1002/pat.597
dc.identifier.endpage412
dc.identifier.issn1042-7147
dc.identifier.issn1099-1581
dc.identifier.issue5
dc.identifier.scopus2-s2.0-18944392345
dc.identifier.scopusqualityQ2
dc.identifier.startpage405
dc.identifier.urihttps://hdl.handle.net/11729/184
dc.identifier.urihttp://dx.doi.org/10.1002/pat.597
dc.identifier.volume16
dc.identifier.wosWOS:000229253600008
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakScience Citation Index Expanded (SCI-EXPANDED)en_US
dc.institutionauthorPekcan, Mehmet Önderen_US
dc.institutionauthorid0000-0002-0082-8209
dc.language.isoenen_US
dc.peerreviewedYesen_US
dc.publicationstatusPublisheden_US
dc.publisherJohn Wiley & Sons Ltden_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectIntramolecular excimersen_US
dc.subjectPhoton transmissionen_US
dc.subjectPolymer interfacesen_US
dc.subjectVoid closureen_US
dc.subjectFluorescenceen_US
dc.subjectDiffusionen_US
dc.subjectInterdiffusionen_US
dc.subjectDispersionsen_US
dc.subjectChainen_US
dc.subjectWateren_US
dc.subjectVoidsen_US
dc.subjectInterdiffusionen_US
dc.subjectExcimeren_US
dc.subjectPolystyreneen_US
dc.subjectAnnealingen_US
dc.subjectEmulsion polymerizationen_US
dc.subjectFilm preparationen_US
dc.subjectGlass transitionen_US
dc.subjectLatexesen_US
dc.subjectMonomersen_US
dc.subjectNanostructured materialsen_US
dc.subjectSurface active agentsen_US
dc.subjectFilm formationen_US
dc.subjectNano-sized polystyrenesen_US
dc.subjectSteady state fluorescence (SSF)en_US
dc.subjectPolystyrenesen_US
dc.titleFilm formation from nano-sized polystyrene latex particlesen_US
dc.typeArticleen_US
dspace.entity.typePublication

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