Elucidation of the complete set of H-2 electronic states' vibrational data
Yükleniyor...
Dosyalar
Tarih
2004-11
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Pergamon-Elsevier Science Ltd
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
We have previously established that, the vibration period T of a diatomic molecule, can be expressed as T = [4pi(2)/(rootninjh)]rootgM(0)m(e)r(2), where M-0 is the reduced mass of the nuclei, M-e the mass of the electron, r the internuclear distance of the molecule at the given electronic state, It the Planck Constant, and g a dimensionless and relativistically invariant coefficient, which appears to be a characteristic of the electronic configuration of the molecule. Herein we validate this relationship, chiefly on the basis of vibrational data of H-2 molecule's electronic states, and achieve its calibration, vis-a-vis the quantum numbers that it is to involve. This, basically yields, the elucidation of the complete set of H-2 spectroscopic data. Thus, the composite quantum number n(1)n(2) along our finding is nothing but the ratio of the internuclear distance r at the given electronic state, to the internuclear distance r(0) at the ground state. This makes that for electronic states configured alike, for which g is expected to remain the same, T-2 versus r(3), should exhibit a linear behavior. Our approach can well be applied to other molecules.
Açıklama
Anahtar Kelimeler
Hydrogen molecule, Electronic states, Calibration, Electron energy levels, Electronic structure, Hydrogen bonds, Mathematical models, Molecular vibrations, Quantum theory, Electronic configuration, Electronic states, Hydrogen molecules, Planck constant, Hydrogen
Kaynak
International Journal of Hydrogen Energy
WoS Q Değeri
Q1
Scopus Q Değeri
Q1
Cilt
29
Sayı
14
Künye
Yarman, N. T. (2004). Elucidation of the complete set of H 2 electronic states’ vibrational data. International Journal of Hydrogen Energy, 29(14), 1521-1526. doi:10.1016/j.ijhydene.2004.02.006
