Effect of annealing rate on film formation from poly(vinyl acetate) latex particles

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dc.authorid0000-0001-8679-0530
dc.authorid0000-0002-6293-1359
dc.authorid0000-0002-0082-8209
dc.contributor.authorArda, Ertanen_US
dc.contributor.authorKara, Selimen_US
dc.contributor.authorPekcan, Mehmet Önderen_US
dc.date.accessioned2015-01-15T23:01:07Z
dc.date.available2015-01-15T23:01:07Z
dc.date.issued2008
dc.departmentIşık Üniversitesi, Fen Edebiyat Fakültesi, Fizik Bölümüen_US
dc.departmentIşık University, Faculty of Arts and Sciences, Department of Physicsen_US
dc.description.abstractThe photon transmission technique was used to monitor the time and temperature evolution of film formation from poly(vinyl acetate) (PVAc) latex particles. The latex films were prepared below the glass transition temperature (T-g) of PVAc. These films were annealed at various annealing rates above the Tg of PVAc. It was observed that transmitted photon intensity (I-tr) from these films increased at all annealing rates as the annealing time and temperature are increased. The increase in the I-tr is attributed to the increase in crossing density at the junction surface. The healing points (tau(H), T-H) were determined for various annealing rates and the healing activation energy (Delta H) was measured and found to be 43.4 kcal/mol. The interdiffusion (backbone) activation energies (Delta E) and reptation frequencies (nu) of PVAc chains were measured. The averaged value of Delta E was found to be 226.6 kcal/mol. It is observed that Delta E is unchanged but nu is increased as increasing the annealing rates.en_US
dc.description.versionPublisher's Versionen_US
dc.identifier.citationPekcan, M. Ö., Arda, E. & Kara, S. (2008). Effect of annealing rate on film formation from poly(vinyl acetate) latex particles. Composite Interfaces, 15(1), 19-33. doi:10.1163/156855408783431291en_US
dc.identifier.doi10.1163/156855408783431291
dc.identifier.endpage33
dc.identifier.issn0927-6440
dc.identifier.issn1568-5543
dc.identifier.issue1
dc.identifier.scopus2-s2.0-38349137406
dc.identifier.scopusqualityQ2
dc.identifier.startpage19
dc.identifier.urihttps://hdl.handle.net/11729/305
dc.identifier.urihttp://dx.doi.org/10.1163/156855408783431291
dc.identifier.volume15
dc.identifier.wosWOS:000253708100003
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakScience Citation Index Expanded (SCI-EXPANDED)en_US
dc.institutionauthorPekcan, Mehmet Önderen_US
dc.institutionauthorid0000-0002-0082-8209
dc.language.isoenen_US
dc.peerreviewedYesen_US
dc.publicationstatusPublisheden_US
dc.publisherTaylor & Francis Ltden_US
dc.relation.ispartofComposite Interfacesen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectPolymer-polymer interfaceen_US
dc.subjectPhoton transmissionen_US
dc.subjectMolecular-weighten_US
dc.subjectInterdiffusionen_US
dc.subjectTemperatureen_US
dc.subjectDiffusionen_US
dc.subjectReptationen_US
dc.subjectWateren_US
dc.subjectTimeen_US
dc.subjectAnnealingen_US
dc.subjectLatexesen_US
dc.subjectPhotonsen_US
dc.subjectPolyvinyl acetatesen_US
dc.subjectFilm formationen_US
dc.subjectPhoton transmission techniqueen_US
dc.subjectReptation frequencyen_US
dc.subjectThin filmsen_US
dc.titleEffect of annealing rate on film formation from poly(vinyl acetate) latex particlesen_US
dc.typeArticleen_US
dspace.entity.typePublication

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