Characterization of Bulgarian oil shale kerogen revealed by oxidative degradation

Basit Öğe Kaydı
dc.authorid0000-0002-7014-366X
dc.authorid0000-0002-4399-0046
dc.contributor.authorBudinova, Temenuzhka K.en_US
dc.contributor.authorRazvigorova, Mariaen_US
dc.contributor.authorTsyntsarski, Boyko G.en_US
dc.contributor.authorPetrova, Bilyana N.en_US
dc.contributor.authorEkinci, Ekremen_US
dc.contributor.authorYardım, Mehmet Ferhaten_US
dc.date.accessioned2015-01-15T23:01:19Z
dc.date.available2015-01-15T23:01:19Z
dc.date.issued2009
dc.departmentIşık Üniversitesi, Mühendislik Fakültesi, Kimya Mühendisliğien_US
dc.departmentIşık University, Faculty of Engineering, Department of Chemical Engineeringen_US
dc.description.abstractA 13-step alkaline permanganate degradation of Bulgarian oil shale kerogen concentrate at ambient temperature was carried out. A high yield of oxidation products (90.1%) and a low yield of gaseous products (2.79%) were obtained. IR and (1)H NMR spectroscopic studies have shown that two significantly different types of high molecular products are present in kerogen. Further oxidation of these structures leads to the formation of low molecular aliphatic and aromatic acids, proven by gas chromotography (GC) and gas chromatography-mass spectrometry (GC-MS). The data obtained at these mild conditions allow us to acquire detailed information about the aromatic structures and polymethylene chain lengths in kerogen.The 5-step oxidation of the kerogen at 90 degrees C provides information about stable aromatic structures. Soluble and insoluble polyfunctional acids in acid medium have close molecular masses and spectral characteristics. The amount of benzene and naphthalene carboxylic acids is 11.3% of the organic matter of the oil shale.en_US
dc.description.versionPublisher's Versionen_US
dc.identifier.citationBudinova, T., Razvigorova, M., Tsyntsarski, B., Petrova, B., Ekinci, E., & Yardim, M. F. (2009). Characterization of bulgarian oil shale kerogen revealed by oxidative degradation. Chemie Der Erde - Geochemistry - Interdisciplinary Journal for Chemical Problems of the Geosciences and Geoecology, 69(3), 235-245. doi:10.1016/j.chemer.2009.04.001en_US
dc.identifier.doi10.1016/j.chemer.2009.04.001
dc.identifier.endpage245
dc.identifier.issn0009-2819
dc.identifier.issue3
dc.identifier.scopus2-s2.0-68049132861
dc.identifier.scopusqualityQ2
dc.identifier.startpage235
dc.identifier.urihttps://hdl.handle.net/11729/343
dc.identifier.urihttp://dx.doi.org/10.1016/j.chemer.2009.04.001
dc.identifier.volume69
dc.identifier.wosWOS:000269733900003
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakScience Citation Index Expanded (SCI-EXPANDED)en_US
dc.institutionauthorEkinci, Ekremen_US
dc.language.isoenen_US
dc.peerreviewedYesen_US
dc.publicationstatusPublisheden_US
dc.publisherElsevier GMBH, Urban & Fischer Verlagen_US
dc.relation.ispartofChemie Der Erde-Geochemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectBulgarian oil shale kerogenen_US
dc.subjectOxidationen_US
dc.subjectAlkaline permanganateen_US
dc.subjectStructural investigationen_US
dc.subjectResistant bio-polymeren_US
dc.subjectChemical degradationen_US
dc.subjectBotryococcus-brauniien_US
dc.subjectPossible originen_US
dc.subjectOuter wallsen_US
dc.subjectCrude oilsen_US
dc.subjectCadineneen_US
dc.subjectBitumenen_US
dc.subjectMarineen_US
dc.subjectMatteren_US
dc.subjectBenzeneen_US
dc.subjectCarboxylic aciden_US
dc.subjectDegradationen_US
dc.subjectGas chromatographyen_US
dc.subjectKerogenen_US
dc.subjectMass spectrometryen_US
dc.subjectOil shaleen_US
dc.subjectChemical-structureen_US
dc.titleCharacterization of Bulgarian oil shale kerogen revealed by oxidative degradationen_US
dc.typeArticleen_US
dspace.entity.typePublication

Dosyalar

Orijinal paket
Listeleniyor 1 - 1 / 1
Küçük Resim Yok
İsim:
343.pdf
Boyut:
494.74 KB
Biçim:
Adobe Portable Document Format
Açıklama:
Publisher's Version
İndir

Koleksiyon

Makale Koleksiyonu | Enformasyon Teknolojileri Bölümü
Scopus İndeksli Yayınlar Koleksiyonu
WoS İndeksli Yayınlar Koleksiyonu