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Yayın In situ fluorescence study of swelling, sorption and desorption processes in and out of PAAm gels(Wiley-V C H Verlag GMBH, 2008-05) Evingür, Gülşen Akın; Karslı, Kadir; Pekcan, Mehmet ÖnderSmall molecule sorption and desorption in and out of polyacrylamide (PAAm) gels were studied at various temperatures. Pyranine (P(y)) dissolved in water used as a probe. Fluorescence emission intensity, I(p) from P(y) was monitored for studying sorption and desorption processes. Scattered light intensities, I(SC) from PAAm gel was also monitored to observed structural variations during sorption and desorption process. Li-Tanaka model was applied to produce the swelling time constants, tau(C) and sorption coefficients, D(C) for the swelling processes. on the other hand, sorption and desorption processes were studied and coefficients were produced by using Fickian model. Related activation energies were also calculated from the corresponding physical processes.Yayın Studying on the small molecule diffusion into hydrogels: a fluorescence study(Amer Inst Physics, 2007) Evingür, Gülşen Akın; Karslı, Kadir; Pekcan, Mehmet ÖnderIn situ steady state fluorescence experiments (SSF) were reported during the diffusion of water molecules into PAAm in gels at various temperatures. The fluorescence emission intensities, Ip increased continuously as water molecules diffused into gels. I-sc, scattered light intensities, from the gel was also monitored to detect the variation in the gel structure during diffusion process. Swelling and diffusion experiments were quantified by Li-Tanaka and Fickian models.
