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Yayın The composition of acids in bitumen and in products from saponification of kerogen: Investigation of their role as connecting kerogen and mineral matrix(Elsevier Science BV, 2008-11-03) Razvigorova, Maria; Budinova, Temenuzhka K.; Tsyntsarski, Boyko G.; Petrova, Bilyana N.; Ekinci, Ekrem; Atakül, HüsnüIn order to obtain more information and to understand the nature of relation between organic and mineral matter in oil shales, the compositions of soluble bitumen fractions obtained by extraction from Bulgarian oil shales before and after demineralization with 10% HCl, concentrated HE and a HF/HCl mixture were investigated. The four extracts were quantitatively examined by IR and H-1 NMR spectroscopy. The investigation of isolated acidic material of the bitumen fractions showed that the fatty acids are present in bitumen fractions as free acids, esters and salts. The amount of free acids in bitumen is very small. The dominant part of bitumen acids is associated with mineral components of the oil shales as well as part of them is included in the mineral matrix, and can be separated only after deep demineralization. The kerogen of the oil shales, obtained after separation of the bitumen fractions and mineral components, was subjected to saponification in order to determine the amount of acids, bound as esters to the kerogen matrix. The major components found were n-carboxylic, alpha,omega,-di-carboxylic, and aromatic acids. The connection of kerogen with mineral components is accomplished by the participation of carboxylic and complicated ester bonds. Experimental data for the composition of bitumen acids give evidence that algae and terrestrial materials are initial sources in the formation of soluble organic matter of Bulgarian oil shale.Yayın A threefold empirical analysis of the relationship between regional income inequality and water equity using Tapio decoupling model, WPAT equation, and the local dissimilarity index: evidence from Bulgaria(Springer-Verlag GmbH, 2021-01) Taşbaşı, AslıThis study utilizes a threefold empirical analysis in order to examine the relationship between income and water equity in Bulgaria, the fastest shrinking country in the world in terms of population, and the most unequal member of the EU in terms of regional income distribution. First, in line with this goal, the income elasticity of regional water demand in the country is calculated using the Tapio decoupling model. Second, the WPAT equation which measures the weighted impacts of population, per capita income and intensity on water demand, is utilized. And finally, using the local dissimilarity index, spatial differences in access to water by region are measured. Underscoring the essence of regional level analyses based on specific decomposed subgroups, findings are thus compatible with the economic and demographic characteristics of the regions handled in the study. In the northern regions where income and population levels are relatively low, during periods when income and water demand both increase, the rise in water demand is usually higher than the increase in income; conversely, when income decreases, the water demand also falls. The effect of population dominates the changes in water demand in the northern regions, with the exception of the Northwestern Region, where water intensity is the leading factor, possibly because the Balkans’ largest nuclear power plant is located in the region. In the southern regions where income is higher, income has been the most important determinant of water demand, particularly in recent years.Yayın Technical climate change adaptation options of the major ski resorts in Bulgaria(Springer International Publishing, 2016-01-01) Demiroğlu, Osman Cenk; Turp, Mustafa Tufan; Öztürk, Tuğba; An, Nazan; Kurnaz, Mehmet LeventClimate change has been and increasingly will be a major threat to the ski tourism industry, whose survival is highly dependent on the existence of snow cover of sufficient depth and duration. For this matter, it is even now more usual for the ski resorts to adapt to this issue by various measures at the technical, operational, and political levels. Technically speaking, snowmaking has become the method most used throughout the industry to combat the immediate impacts of climate change, while moving the ski areas to higher terrains has been standing out as an another option, wherever available and feasible. In this study, the aim is to project the future climatic changes in snowmaking capacity; in other words, technical snow reliability, and the moving requirements, if any, of the four major ski resorts in Bulgaria for the period of 2016-2030 with respect to the control period of 1991- 2005. For this purpose, the past and the future climatic conditions for the technical snow reliability of the ski resorts and their immediate surroundings are determined by the temperature and the relative humidity values generated and projected through the Regional Climate Model RegCM 4.4 of the Abdus Salam International Centre for Theoretical Physics (ICTP) by scaling the global climate model MPI-ESM-MR of Max Planck Institute for Meteorology down to a resolution of 10 km. The model is further processed according to the recent RCP 4.5 and RCP 8.5 concentration scenarios of the IPCC. The model outputs on air temperature and relative humidity are utilized for determination of wet-bulb temperatures through psychographic conversions that ultimately provide us with thresholds for snowmaking limits. Findings display the temporal changes in the snowmaking hours of the ski resorts at various altitudinal levels calculated according to the environmental lapse rates. Such displays can guide the practitioners in considering investment lives and moving the ski resorts according to optimistic and pessimistic projections.
