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Yayın The composition of acids in bitumen and in products from saponification of kerogen: Investigation of their role as connecting kerogen and mineral matrix(Elsevier Science BV, 2008-11-03) Razvigorova, Maria; Budinova, Temenuzhka K.; Tsyntsarski, Boyko G.; Petrova, Bilyana N.; Ekinci, Ekrem; Atakül, HüsnüIn order to obtain more information and to understand the nature of relation between organic and mineral matter in oil shales, the compositions of soluble bitumen fractions obtained by extraction from Bulgarian oil shales before and after demineralization with 10% HCl, concentrated HE and a HF/HCl mixture were investigated. The four extracts were quantitatively examined by IR and H-1 NMR spectroscopy. The investigation of isolated acidic material of the bitumen fractions showed that the fatty acids are present in bitumen fractions as free acids, esters and salts. The amount of free acids in bitumen is very small. The dominant part of bitumen acids is associated with mineral components of the oil shales as well as part of them is included in the mineral matrix, and can be separated only after deep demineralization. The kerogen of the oil shales, obtained after separation of the bitumen fractions and mineral components, was subjected to saponification in order to determine the amount of acids, bound as esters to the kerogen matrix. The major components found were n-carboxylic, alpha,omega,-di-carboxylic, and aromatic acids. The connection of kerogen with mineral components is accomplished by the participation of carboxylic and complicated ester bonds. Experimental data for the composition of bitumen acids give evidence that algae and terrestrial materials are initial sources in the formation of soluble organic matter of Bulgarian oil shale.Yayın The emergence of projected scaled patterns of extreme temperatures over Europe(Frontiers Media SA, 2023-06-28) Öztürk, Tuğba; Canbaz, Emine; Bilgin, Başak; Matte, Dominic; Kurnaz, Mehmet Levent; Christensen, Jens HesselbjergThis work investigates the scalability of extreme temperatures over the European domain with global warming levels. We have used the EURO-CORDEX ensemble of regional model simulations at 0.11° resolution for daily minimum and maximum temperatures to analyze future changes in extreme weather daily events. Scaling with the annual mean global warming modeled by the driving GCM was applied to future extreme temperature indices changes. Regional changes in each index were scaled by corresponding global warming levels obtained from GCMs. This approach asserts that regional patterns of climate change and average global temperature change are linearly related. It can provide information regarding climate change for periods or emission scenarios when no simulations exist. According to the results, the annual minimum of the lowest temperature of the day (TNn) increases more than the annual maximum of the highest temperature of the day (TXx) for Europe. The multi-model mean of the changes in scaled patterns of extreme temperatures emerges early, around 2020, even before it becomes robust. Individual scaled patterns of TNn and TXx emerge from around 2040.Yayın Simulation of temperature and precipitation climatology for the Central Asia CORDEX domain using RegCM 4.0(Inter-Research, 2012) Öztürk, Tuğba; Altınsoy, Hamza; Türkeş, Murat; Kurnaz, Mehmet LeventThe Coordinated Regional Climate Downscaling Experiment (CORDEX) is a framework designed to coordinate international efforts on regional climate simulations. CORDEX domains encompass the majority of land areas of the world. Region 8 of the CORDEX basically covers Central Asia, with the corners of the domain at 54.76 degrees N, 11.05 degrees E; 56.48 degrees N, 139.13 degrees E; 18.34 degrees N, 42.41 degrees E; and 19.39 degrees N, 108.44 degrees E and with a horizontal resolution of 50 km. In the present study, the results of an experiment with the ICTP regional climate RegCM 4.0 model that was run for seasonal mean air temperature and precipitation total series are presented. The experiment consists of one simulation from 1989 to 2010 using ERA-Interim reanalysis data as the boundary condition, another simulation for the period 1970-2000 using the global climate model ECHAM5 A1B scenario data for forcing, and finally a simulation for the period 2070-2100 using the ECHAM5 A1B scenario projection data for forcing. Between these 3 simulations we determined the temperature and precipitation climatology obtained from RegCM 4.0 downscaling for Region 8 of the CORDEX framework. In spite of the diverse topography of the region, the temperature and precipitation climatology obtained by RegCM 4.0 from hindcast data captures the general characteristics of the climate of Central Asia. In winter, the warm temperature bias of the forcing data is slightly decreased by regional downscaling. The influences of the Indian monsoon system are well represented, as this region covers a large area towards the southern boundary of Region 8, even though the focus of this work was to capture the general characteristics of the whole region.
