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  • Yayın
    Synthesis and liquid crystalline behavior of random copolymer of poly(ethylene oxide) macromonomer and liquid crystalline monomer by the photon transmission technique
    (Taylor & Francis Inc, 2005-12) Yıldız, Sevtap; Yılmaz, Faruk; Özbek, Haluk; Pekcan, Mehmet Önder; Ito, Koichi; Yağcı, Yusuf
    Random copolymers of poly(ethylene oxide) macromonomer with p-vinylbenzyl end-functional group (PEOVB) and liquid crystalline monomer, namely 6-(4-cyanobiphenyl-4'-oxy)hexyl acrylate (COA), were prepared by conventional free radical polymerization. A living anionic polymerization technique was employed for the synthesis of PEO macromonomers bearing p-vinylbenzyl moiety at one end. The photon transmission method was also applied to study the phase transitions of COA monomer and its random copolymer with PEO. It was found that, for both samples, the nematic-smectic A transition is continuous, but the critical fluctuation regions do not allow to obtain 3D XY values. Instead, we have obtained the values close to mean field regime. Scaling of thermal hystersis for random copolymer sample near the nematic-isotropic transition was studied as well. Thermal hysteresis loops were produced under linearly varying temperature. It was shown that the areas of the hysteresis loops scale with the temperature scanning rate with an exponent being equal to 0.614 which is in good agreement with the field-theoretical value.
  • Yayın
    A new method for the source localization in sectionally homogeneous bounded domains involving finitely many inner interfaces of arbitrary shapes
    (Pergamon-Elsevier Science, 2001-05) İdemen, Mehmet Mithat; Alkumru, Ali
    A new method to localize a static point source buried in a nonhomogeneous bounded domain composed of finitely many homogeneous parts separated by interfaces of arbitrary shapes was established. The source can be a simple point charge or current or a dipole of them. The method requires only the knowledge of the potential function Phi (x, y, z) at five or six points on the outermost interface depending on whether the source is simple or dipole. The new and basic feature of the method consists of determining the potential function Phi (0)(x, y, z) which would be observed if the whole space was filled with a homogeneous material. Then, in the case of a simple source, the position P-0 as well as the strengths can be determined, in general, by solving a system of three linear algebraic equations. When the source consists of a dipole, its position P-0 and moment (p) over right arrow can be found by solving a system of six nonlinear algebraic equations. The determination of Phi (0) P-0 and s (or (p) over right arrow) is achieved iteratively by solving the above-mentioned algebraic equations along with a singular integral equation satisfied by Phi (0) Some illustrative examples show the applicability and accuracy of the method. The method can have effective applications in heat conduction, matter diffusion, electrostatics, steady-state current flow, electroencephalography, electrocardiography, etc.
  • Yayın
    Sustainability via extended warranty contracts: design for a consumer electronics retailer
    (MDPI, 2024-01) Aksezer, Sezgin Çağlar
    Warranty is one of the most important attributes of any product, from both manufacturer and consumer points of view. Although the retailers connect manufacturers to customers by selling goods, traditionally, they have isolated themselves from warranty-related matters such as customer complaints and maintenance costs. However, recent trends in consumer behavior toward extended warranty contracts have changed this approach. While retailers have started to generate considerable revenue from the sale of these contracts, sustainability is also achieved by longer product life cycles. This study analyzed the failure behavior of different classes of cell phone products and their related costs through a chain of consumer electronics retailer operating in Türkiye. To compete on pricing and customer service, a novel policy was designed for the retailer to honor the contracts in house rather than underwriting to a third party insurer as the industry standard. The maintenance records of 328 previous failures were analyzed to plot a failure model. Failure mode and effects analysis was carried out to identify failure classes and the respective costs for extended warranty design for cell phones. The expected warranty costs for coverage of the third, fourth, and fifth years of operation were determined. The results show that the retailer may achieve the same level of profit by increasing customer satisfaction along with the sustainability of the product through repair actions.
  • Yayın
    Small molecule diffusion into swelling Iota-Carrageenan gels: A fluorescence study
    (Taylor & Francis Group, 2007-04) Ataman, Evren; Pekcan, Mehmet Önder
    Small molecule diffusion into Iota-Carrageenan gel was studied by using steady-state fluorescence (SSF) technique. Pyranine, dissolved in water was used as fluorescence probe. Fluorescence emission intensity, I-p, and scattered light intensity, I-sc, were monitored to study diffusion and swelling processes at various temperatures respectively. Fickian and Li-Tanaka models were elaborated to produce diffusion, D, and collective diffusion, D-0, coefficients. Diffusion and swelling activation energies were also obtained and found to be 20.5 kj mol(-1) and 28.2 kj mol(-1). respectively.
  • Yayın
    Normative data and factorial structure of the Turkish version of the junior temperament and character inventory-revised
    (Taylor & Francis, 2017) Köse, Samet; Çam Çelikel, Feryal; Akın, Ercan; Kaya, Cahit; Elbozan Cumurcu, Birgül; Etikan, İlker; Cloninger, Claude Robert
    Objective: Junior Temperament and Character Inventory (J-TCI) was developed by Luby, Svrakic, McCallum, Przybeck, and Cloninger based on Cloninger's biopsychosocial model to assess temperament and character dimensions in children and adolescents. Methods: The Turkish version of J-TCI-Revised (J-TCI-R) was administered to 1129 elementary and middle-school (male/female, 546/583) students. Internal consistency reliabilities were measured by Cronbach's alpha; test-retest was assessed across one month. Results: Cronbach's alphas for the subscales of J-TCI-R ranged from 0.60 to 0.75 for temperament and character subscales, which were comparable to US and other populations. The correlations between baseline and one month after administration of J-TCI-R were highly and statistically significant (r = 0.578-0.674 for scales and 0.366-0.582 for subscales) (n = 795). Factor analysis results using Eigenvalue greater than one rule indicated three out of four factors for temperament scales and one out of two factors for character subscales which were similar to findings from the other countries. When all of the subscales were subjected to factor analysis, four out of six factors were retained. To our knowledge, this is the first study analysing psychometric properties and factorial construct of the J-TCI-R. Conclusions: The internal reliability coefficients and test-retest indicated a good stability of scores over time and the factorial structure was consistent with Cloninger's model of personality. The reliability and validity of the Turkish version of the TCI is therefore supported.
  • Yayın
    Evolutionary route to diploidy and sex
    (National Academy of Sciences, 2001-11-20) Tüzel, Erkan; Sevim, Volkan; Erzan, Ayşe
    By using a bit-string model of evolution, we find a successful route to diploidy and sex in simple organisms. Allowing the sexually reproducing diploid individuals to also perform mitosis, as they do in a haploid-diploid cycle, leads to the complete takeover of the population by sexual diploids. This mechanism is so robust that even the accidental conversion and pairing of only two diploids give rise to a sexual population.
  • Yayın
    Synergistic effect of the locust bean gum on the thermal phase transitions of kappa-carrageenan gels
    (Elsevier Sci Ltd, 2009-03) Arda, Ertan; Kara, Selim; Pekcan, Mehmet Önder
    Synergism between K-carrageenan and locust bean gum (LBG) was studied using the photon transmission technique. Synergistic effects in these polymeric mixtures strongly affected the physical properties of the gel structure. The transmitted light intensities, I-tr, versus temperature variations were investigated during the gelation and liquefaction processes. Slight synergistic peaks were detected in gel-sol and sol-gel transition temperatures for high kappa-carrageenan/LBG ratios (approx. 80/2). Moreover, apparent synergistic peaks were observed in gel-sol and sol-gel transition activation energies for the mixtures approximately with the ratios of 80/10.
  • Yayın
    Progressive damage analyses of masonry buildings by dynamic analyses
    (Springer International Publishing AG, 2020-08) Aras, Fuat; Akbaş, Tolga; Ekşi, Hızır; Çeribaşı, Seyit
    This study investigates the effects of prescribed damage on the walls of masonry buildings by experimental and numerical methods. Ambient vibration survey method was applied to an existing, two-story, unreinforced masonry building to determine its dynamic characteristics, such as mode shapes and natural frequencies. Then, the walls on two exterior sides of the building were demolished, and dynamic testing was repeated for the damaged building. As the next step, the amount of damage on the building was increased by more impacts, and the dynamic characteristics of the heavily damaged building were identified. The results obtained from the undamaged, damaged and heavily damaged building were compared, and the damage effect on the natural frequencies of the building was noted. Besides, finite element analyses of the undamaged, damaged and heavily damaged buildings were performed. It was found that, the numerical models, constructed with code-based material properties, do not sufficiently represent the dynamic behavior of masonry buildings. Secondly, as the result of the sustained damage, while the experimental and the numerical modal analyses revealed the decrease in the dominant frequencies of the building, the difference between them increases with the severity of the damage. With the framework presented in this study, the behavior of masonry buildings can better be determined and used for analysis purposes.
  • Yayın
    Future projections of temperature and precipitation climatology for CORDEX-MENA domain using RegCM4.4
    (Elsevier Science Inc, 2018-07-01) Öztürk, Tuğba; Turp, Mustafa Tufan; Türkeş, Murat; Kurnaz, Mehmet Levent
    In this study, we investigate changes in seasonal temperature and precipitation climatology of CORDEX Middle East and North Africa (MENA) region for three periods of 2010-2040, 2040-2070 and 2070-2100 with respect to the control period of 1970-2000 by using regional climate model simulations. Projections of future climate conditions are modeled by forcing Regional Climate Model, RegCM4.4 of the International Centre for Theoretical Physics (ICTP) with two different CMIP5 global climate models. HadGEM2-ES global climate model of the Met Office Hadley Centre and MPI-ESM-MR global climate model of the Max Planck Institute for Meteorology were used to generate 50 km resolution data for the Coordinated Regional Climate Downscaling Experiment (CORDEX) Region 13. We test the seasonal time-scale performance of RegCM4.4 in simulating the observed climatology over domain of the MENA by using the output of two different global climate models. The projection results show relatively high increase of average temperatures from 3 degrees C up to 9 degrees C over the domain for far future (2070-2100). A strong decrease in precipitation is projected in almost all parts of the domain according to the output of the regional model forced by scenario outputs of two global models. Therefore, warmer and drier than present climate conditions are projected to occur more intensely over the CORDEX-MENA domain.
  • Yayın
    Numerical calculations of relativistic electron drift loss effect
    (Amer Geophysical Union, 2008-09-09) Kim, Kyung Chan; Lee, Daeyoung; Kim, Heejeong; Lyons, Larry R.; Lee, Ensang; Öztürk, Mehmet Kaan; Choi, Cheongrim
    It has been suggested that drift loss to the magnetopause can be one of the major loss mechanisms contributing to relativistic electron flux dropouts. In this study, we examine details of relativistic electrons' drift physics to determine the extent to which the drift loss through the magnetopause is important to the total loss of the outer radiation belt. We have numerically computed drift paths of relativistic electrons' guiding center for various pitch angles, various measurement positions, and different solar wind conditions using the Tsyganenko T02 model. We specifically demonstrate how the drift loss effect depends on these various parameters. Most importantly, we present various estimates of relative changes of the omnidirectional flux of 1 MeV electrons between two different solar wind conditions based on a simple form of the directional flux function. For a change of the dynamic pressure from 4 nPa to 10 nPa with a fixed IMF B-Z = 0 nT, our estimate indicates that after this increase in pressure, the equatorial omnidirectional flux at midnight near geosynchronous altitude decreases by similar to 56 to similar to 97%, depending on the specific pitch angle dependence of the directional flux. The effect rapidly decreases at regions earthward of geosynchronous orbit and shows a general trend of decrease away from midnight. For a change of the IMF BZ from 0 nT to -15 nT with a fixed dynamic pressure of 4 nPa, the relative decrease of the omnidirectional flux at geosynchronous altitude on the nightside is much smaller than that for the pressure increase, but its effect becomes substantial only beyond geosynchronous orbit. Possibilities exist that our results may change to some extent for a different magnetospheric model than the one used here.