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Yayın Coupled influence of content, gradation and shape characteristics of silts on static liquefaction of loose silty sands(Elsevier Sci Ltd, 2017-10) Monkul, Mehmet Murat; Etminan, Ehsan; Şenol, AykutStatic liquefaction is a challenging problem of geotechnical engineering as its consequences are generally catastrophic when they occur on site. Previous laboratory studies focused on various factors that could influence the static liquefaction potential of silty sands. Most popular of those investigated factors are stress conditions, deposition method and fines content. The purpose of the present study is to investigate the other possible factors, of which very little is known, mainly focusing on the silt characteristics including grain size distribution, relative size, and shape effects of the silt grain matrix within the sand. Undrained monotonic triaxial compression tests were conducted on thirty sands with varying fmes contents, which were prepared by mixing three base sands (Sile Sands 20/30, 50/55, 80/100) with same geologic origin but with different gradations and three different non-plastic silts (IZ, SI and TI' silts) with different gradations and shape characteristics. The experimental results revealed that each of the mentioned factors had their own influence on static liquefaction behavior of sands. The static liquefaction potential of all the three sands in this study was observed to increase with decreasing coefficient of uniformities of the silt grain matrix (CUsiit) in sands. For a particular base sand, static liquefaction potential was observed to increase with decreasing mean grain diameter ratio (D-50.sand/d(50.silt)) due to change of silt gradation. However, shape characteristics of the silt grains are also found to be another important factor, in certain cases observed to have a greater influence than mean grain diameter ratio criterion. As an example, it was shown that at the same FC, base sand, depositional energy and consolidation stress, angular nature of TT silt potentially caused more meta-stable contacts (weaker grain contacts that promote excess pore pressure generation during shearing) within the specimens than sub-rounded SI silt, which caused specimens with TT silt to be more liquefiable than their counterparts with SI silt. Moreover, it was found that there is a coupled relationship between the fines content and investigated silt characteristics (gradation, mean size, shape effects) on the static liquefaction behavior of sands. The unexpected trend regarding the last finding is that the mentioned influence of silt characteristics (i.e. gradation, size and shape) on static liquefaction of sands becomes more considerable with decreasing fines content at loose states.Yayın Synergistic effect of the locust bean gum on the thermal phase transitions of kappa-carrageenan gels(Elsevier Sci Ltd, 2009-03) Arda, Ertan; Kara, Selim; Pekcan, Mehmet ÖnderSynergism between K-carrageenan and locust bean gum (LBG) was studied using the photon transmission technique. Synergistic effects in these polymeric mixtures strongly affected the physical properties of the gel structure. The transmitted light intensities, I-tr, versus temperature variations were investigated during the gelation and liquefaction processes. Slight synergistic peaks were detected in gel-sol and sol-gel transition temperatures for high kappa-carrageenan/LBG ratios (approx. 80/2). Moreover, apparent synergistic peaks were observed in gel-sol and sol-gel transition activation energies for the mixtures approximately with the ratios of 80/10.Yayın Film formation from pure and mixed latices; transient fluorescence study(Academic Press Inc Elsevier Science, 2005-11-15) Uğur, Şaziye; Pekcan, Mehmet ÖnderA fast transient fluorescence technique was used to study latex film formation induced by organic solvent vapor. Mixtures of pyrene (P)- and naphthalene (N)-labeled and/or pure naphthalene-labeled latex films were prepared separately from poly(methyl methacrylate) (PMMA) particles. Then these pure and mixed latex films were exposed to vapor of various chloroform-heptane mixtures in seven different experiments. In both films, fluorescence lifetimes from N were monitored during vapor-induced film formation. It was observed that N lifetimes decreased as the vapor exposure time is increased. A Stern-Volmer kinetic analysis was used for low quenching efficiencies to interpret the decrease in N lifetimes. A Prager-Tirrell model was employed to obtain back-and-forth frequencies, v, of reptating PMMA chains during latex film formation induced by solvent vapor. In both pure and mixed latex films, v values were found to be correlated with the chloroform content in the vapor mixture. It was observed that polymer interdiffusion obeyed a t(1/2) law during film formation.Yayın A phase diagram near the NAC point in liquid crystals(Elsevier Science SA, 2002-07-28) Salihoğlu, Selami; Yurtseven, Hamit; Enginer, YücelIn this study using a mean field model we obtain the phase line equations for the NA. NC and AC transitions near the NAC point in a mixture of liquid crystals. We then fit these phase line equations to the experimental data. This fitting shows that our theoretical phase diagram predicts the correct experimental behaviour of the phase diagram in a mixture of liquid crystals.
