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Yayın Small molecule diffusion into swelling Iota-Carrageenan gels: A fluorescence study(Taylor & Francis Group, 2007-04) Ataman, Evren; Pekcan, Mehmet ÖnderSmall molecule diffusion into Iota-Carrageenan gel was studied by using steady-state fluorescence (SSF) technique. Pyranine, dissolved in water was used as fluorescence probe. Fluorescence emission intensity, I-p, and scattered light intensity, I-sc, were monitored to study diffusion and swelling processes at various temperatures respectively. Fickian and Li-Tanaka models were elaborated to produce diffusion, D, and collective diffusion, D-0, coefficients. Diffusion and swelling activation energies were also obtained and found to be 20.5 kj mol(-1) and 28.2 kj mol(-1). respectively.Yayın Swelling activation energy of kappa-carrageenan in its gel state: A fluorescence study(John Wiley & Sons Inc, 2007-12-15) Tarı İlgin, Özlem; Pekcan, Mehmet ÖnderA steady-state fluorescence technique was employed to study the swelling Of K-carrageenan gels at various temperatures. Pyranine was used as a fluorescence probe. The fluorescence intensity of pyranine was measured during the in situ swelling process of K-carrageenan gels. The fluorescence intensity increased exponentially as the swelling time increased. The increase in the fluorescence intensity was modeled with the Li-Tanaka equation, from which the swelling time constants and cooperative diffusion coefficients were determined. The swelling time constants decreased and the cooperative diffusion coefficients increased as the swelling temperature was increased. The swelling activation energies were measured to be 47.05 kJ/mol.Yayın Reordering of polystyrene gel due to multiple swelling in organic vapor fast transient fluorescence technique study(Elsevier Science SA, 2006-07-31) Erdoğan, Matem; Pekcan, Mehmet ÖnderReordering of disc-shaped polystyrene (PS) gels due to multiple swelling, under organic vapor was studied by using Fast Transient Fluorescence (FTRF) technique. Disc-sbaped polystyrene gels were prepared by free radical copolymerization (FRC) of styrene (S) with ethylene glycol dimethacrylate (EGDM) as a crosslinker. Pyrene (P) was introduced as a fluorescence probe during polymerization. Swelling experiments were performed by using P doped PS gels under chloroform vapor. After each swelling step, gels were left to dry in an oven at 30 degrees C for consecutive reswelling experiments. Decay curves of P were measured and pyrene lifetimes, tau, were determined. It was observed that tau values decreased as swelling recycles were repeated. It was observed that after the fifth swelling step, two different regimes appeared in the swelling processes in PS gels. Swelling time constant, tau(c), and cooperative diffusion coefficients, D-c were determined by using Li-Tanaka equation for each swelling step in both regimes. It was observed that D-c values decreased up to tenth swelling step and then remained unchanged in both regimes.Yayın Dissolution of Al2O3-polystyrene latex composites: A fluorescence study(Taylor & Francis Ltd, 2005) Uǧur, Şaziye; Tepehan, Fatma Zehra; Pekcan, Mehmet ÖnderThis work reports the use of the steady state fluorescence (SSF) technique to study dissolution of a composite film formed from a mixture of Al 2O3 and polystyrene (PS) latex particles. The composite films were cast from dispersion of pyrene (P)-labeled PS particles in Al 2 O3 solution at room temperature and annealed at 280°C temperature for 10 min. Eight different composite films were studied in various latex contents. Toluene was used as dissolution agent. Fluorescence intensities Ip from P were monitored during dissolution. Fickian diffusion was employed to model the dissolution processes. Dissolution coefficients, D d, were measured and found to be increased at high PS content in the composite films.Yayın Determination of pre-gelation and post-gelation activation energies during free radical crosslinking copolymerization(Taylor & Francis Ltd, 2005) Kaya Aktaş, Demet; Pekcan, Mehmet ÖnderSteady-state fluorescence (SSF) and dilatoraetric techniques were used to study the free-radical crosslinking copolymerization (FCC) of styrene (S) and divinylbenzene (DVB) in bulk. The gel points (t g) were recorded by dilatometry at various DVB contents and temperatures in pre-gelation regime during FCC process. Pyrene (Py) was used as a fluorescence probe for the in situ polymerization experiments. The time required for a sudden increase in the fluorescence intensity of Py was recorded for the samples at various DVB contents and temperatures. Py fluorescence intensity during FCC exhibits a sudden increase corresponding to the reaction time at which the rate of polymerization becomes maximum due to the gel effect in post-gelation regime. The onset of gel effect point (t ge) was determined for various DVB contents and temperatures. The results show that alhough the dilatometric technique recorded the gel point, the fluorescence technique can be used to monitor the onset of the gel effect during S–DVB copolymerization. Pre-gelation and post-gelation actuation energies. ?E pre and ?E post were measured and it is observed that pre-gelation regime needs smaller energies than post-gelation regime during FCC.
