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Yayın Investigating the thermally transferred optically stimulated luminescence source trap in fired geological quartz(Pergamon-Elsevier Science Ltd, 2014-03) Koul, Dileep K.; Patil, Pravinkumar G.; Oniya, Ebenezer O.; Polymeris, George S.The pre-dosed thermoluminescence (TL) emission of quartz has been found to be useful in retrospective dosimetry and archaeometry. Though the pre-dosed optically stimulated luminescence (OSL) and emissions have been reported to be similar, the former has been found to be un-reliable for the equivalent dose estimation. As this measurement protocol involves thermal heating at around 400 degrees C, the work reported in this paper investigated the influence of this heating on the OSL using fired specimens from various regions. The results suggested that the discrepancy in the behaviour of two emissions is caused by the presence of the thermally transferred optically stimulated luminescence (TT-OSL) induced by thermal-activation involved in the pre-dose treatment. This transferred signal was observed to be very significant in the case of samples containing a prominent higher-temperature TL peak at similar to 375 degrees C. The characterization of this signal based on (i) the nature of the glow curves, (ii) thermal-annealing of the OSL trap, (iii) observation of the TT-OSL, (iv) bleaching of the source trap and (v) the correlation between TL and OSL seems to suggest that the trap corresponding to this TL peak is the source trap in the TT-OSL emission mechanism.Yayın Theory of fluidity of liquids, glass transition, and melting(Elsevier B.V., 2006-03-01) Dimitrov, Ventzislav IvanovThis is a presentation of a rigorous theory of fluidity of liquids, glass transition and melting of solids in the frame of an asymmetric double well potential model. Potential wells are doubled time to time by the local density fluctuations caused by the thermal longitudinal waves. The average frequency of doubling of potential wells is equal to the frequency of the most energetic waves which obey a law similar to Wein's displacement law in black body radiation. Based on the equilibrium thermodynamic theory of fluctuations and the displacement law, a law of linear pre-diffusion mean-square displacement of particles in a solid is derived: the mean-square displacement of molecules within their potential wells increases linearly with temperature. It is shown that when this is broken-down (where the mean-square displacement at a certain temperature rapidly changes its slope as a function of temperature) glass devitrifies and crystal melts, and all possible solid-liquid transitions of a substance occur at the same critical mean-square displacement: any solid (not only crystals) transforms into liquid when the mean-square displacement, as a fraction of the average intermolecular distance, acquires a certain universal critical value - the same for different substances. It is proved that molecules in a liquid perform specific Brownian motion. The average jump distance is a function of temperature and it is much smaller than the nearest intermolecular distances. At a certain temperature, shown to be the Kauzmann temperature, the average jump distance of Brownian motion becomes equal to zero: the supercooled liquid undergoes glass transition. The transition was proven to be a phase transition of the fourth order: the free energy of the system and its first, second and third derivatives are all continuous functions, but its fourth derivative with respect to temperature is discontinuous. Molecular mobility, diffusion and viscosity are obtained as functions of temperature.Yayın Investigation of OSL signals from very deep traps in unfired and fired quartz samples(Elsevier Science BV, 2010-03-15) Kitis, George; Güneç Kıyak, Nafiye; Polymeris, George S.; Pagonis, VasilisThis paper presents an attempt to isolate experimentally optically stimulated luminescence (OSL) signals which may originate from very deep traps (VDT) in quartz samples. As VDT we consider those traps which are responsible for TL glow peaks with a peak maximum temperature above a TL readout temperature of 500 C. The basic experimental procedure used to isolate OSL signals from VDT is heating the quartz samples to 500 C immediately before measuring the OSL signal. The study was carried out on eight quartz samples of very different origins; it is found that all eight samples exhibit OSL signals from VDT, and for a wide region of OSL stimulation temperatures. The OSL signal from VDT depends strongly on the type of quartz sample studied and on whether the sample was fired at high temperatures or not. The behavior of the OSL signal from VDT as a function of the stimulation temperature is found to be very different in fired and unfired samples. The thermal activation energy E for the OSL signals from VDT is obtained in both fired and unfired samples. The OSL signal from VDT in quartz samples fired at 800 C for 1 h is very high, and the OSL curves consist of three well-defined components and a fourth slow component which is rather poorly resolved. The dose response of these components is obtained using a computerized deconvolution procedure for the dose region 0.5-300 Gy. The results are of importance for dating of ancient fired ceramics, since OSL signals from VDT could potentially extend appreciably the equivalent dose region toward both lower and higher values.Yayın Thermal quenching of thermoluminescence in quartz samples of various origin(Elsevier Science BV, 2011-03-15) Subedi, Bhagawan; Oniya, Ebenezer O.; Polymeris, George S.; Afouxenidis, Dimitrios; Tsirliganis, Nestor C.; Kitis, GeorgeThe effect of thermal quenching stands among the most important properties in the thermoluminescence (TL) of quartz on which many applications of TL are based. Since the quartz samples used in various applications are all of different origin it is useful to investigate whether the values of the thermal quenching parameters, i.e. the activation energy for thermal quenching W and a parameter C which describes the ratio of non-radiative to radiative luminescence transitions, evaluated mainly in specific quartz samples can be extrapolated to quartz samples of unknown origin as well as to quartz samples which are annealed at high temperatures. In the present work the TL glow curve of a series of un-annealed and annealed natural and synthetic quartz samples were studied as a function of the heating rate between 0.25 K/s and 16 K/s. Using an indirect fitting method it was found that the thermal quenching parameters W and C in most of the quartz samples are very similar to the values accepted in the literature. Furthermore, in some cases the thermal quenching parameters Wand Care not the same for all TL glow-peaks in the same glow-curve. Finally, the strong external treatment of annealing the quartz samples at very high temperature can also influence at least one of the thermal quenching parameters.Yayın Spatial econometric analysis of the ecological footprint of European countries(Istanbul University Press, 2024) Demirci, Beyda; Yerdelen Tatoğlu, FerdaThis study explains the effects of various economic factors on the ecological footprint of 34 European countries in 2022 using spatial econometric techniques. Unlike previous studies on the ecological footprint, this study presents more comprehensive results by including spatial effects in the model using spatial econometric techniques for 34 countries for 2022. This study analyzes the lagged effects of per capita GDP growth, trade openness, and renewable energy use on the ecological footprint. The spatial Durbin Model was confirmed as the most appropriate through diagnostic tests and selection criteria. The results show that per capita GDP growth, trade openness, and renewable energy usage positively and significantly affect the ecological footprint. Additionally, the spatially lagged per capita GDP growth rate has a negative impact on the ecological footprint, while the spatially lagged trade openness has a positive impact, both of which are statistically significant. These findings underscore the importance of considering the environmental impacts of economic policies to of spatial effects in the spread of ecological footprints highlights level but also in relation to neighbouring countries.Yayın Drought analysis in the Seyhan River Basin based on standardized drought indices using a new approach considering seasonality(Springer Science and Business Media Deutschland GmbH, 2025-01) Terzi, Tolga Barış; Önöz, BihratDrought is a significant natural disaster with adverse effects on both social and ecological systems. Unlike other natural disasters, drought develops slowly and gradually, complicating its early detection and often resulting in severe impacts on affected regions. Consequently, accurate and dependable drought monitoring is essential for devising effective mitigation strategies. Standardized drought indices are vital tools in drought monitoring, providing a means to quantify and characterize drought events. Most standardized drought indices utilize the Standardized Precipitation Index (SPI) method, which is valued for its simplicity and flexibility. However, this study contends that the SPI method lacks several critical elements, particularly in practice, such as determining the most suitable probability distribution for hydrometeorological variables. Therefore, this study proposes a novel methodology for calculating standardized drought indices and assesses its performance against conventional and nonparametric standardized indices, employing various methods capable of capturing complex dependencies. The novel methodology involves identifying the best-fit probability distributions for each data group through various goodness-of-fit tests. This approach ensures that each group is modeled optimally, considering the seasonal variations inherent to each group. The Seyhan River Basin has been chosen as a case study for the proposed methodology. The drought characteristics of the basin are analyzed using indices derived from the new methodology, the conventional SPI method, and the nonparametric method. Additionally, trend analyses were performed on the calculated indices to identify any directional changes in drought patterns within the Seyhan River Basin. The performance of the proposed methodology was evaluated by analyzing its relationship with nonparametric standardized indices and comparing it to the relationship between conventional standardized indices and nonparametric standardized indices. The results show that the newly proposed methodology outperforms the conventional SPI method across various dependence measures, suggesting it captures the underlying data structure more effectively than the SPI method.
