Breakdown of the Stokes-Einstein relation in supercooled liquids

dc.contributor.authorDimitrov, Ventzislav Ivanoven_US
dc.date.accessioned2015-07-14T23:48:27Z
dc.date.available2015-07-14T23:48:27Z
dc.date.issued2004
dc.departmentIşık Üniversitesi, Fen Edebiyat Fakültesi, Fizik Bölümüen_US
dc.departmentIşık University, Faculty of Arts and Sciences, Department of Physicsen_US
dc.description.abstractBreakdown of the Einstein-Stokes relation in undercooled liquids is one of the unsolved problems in the theory of liquids. The self-diffusion coefficient follows the temperature dependence of the Einstein-Stokes equation D = kT / 6pietar at high temperatures but only down to approximately 1.2T(g) (T-g - glass-temperature). Below 1.2T(g) the temperature behavior of the diffusion coefficient is weaker than 1/eta. In the present study we show that this is a consequence of increasing correlations in the Brownian motion of the constituting particles of the liquid. We derive a relation, which includes the Einstein-Stokes equation as a limiting case for high temperatures.en_US
dc.description.versionPublisher's Versionen_US
dc.identifier.citationDimitrov, V. I. (2004). Breakdown of the Stokes-Einstein relation in supercooled liquids. Journal of Metastable and Nanocrystalline Materials, 20-21, 541-545. doi:10.4028/www.scientific.net/JMNM.20-21.541en_US
dc.identifier.doi10.4028/www.scientific.net/JMNM.20-21.541
dc.identifier.endpage545
dc.identifier.isbn087849944X
dc.identifier.issn1422-6375
dc.identifier.scopus2-s2.0-8644227798
dc.identifier.scopusqualityN/A
dc.identifier.startpage541
dc.identifier.urihttps://hdl.handle.net/11729/666
dc.identifier.urihttp://dx.doi.org/10.4028/www.scientific.net/JMNM.20-21.541
dc.identifier.volume20-21
dc.identifier.wosWOS:000223641200084
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakConference Proceedings Citation Index – Science (CPCI-S)en_US
dc.institutionauthorDimitrov, Ventzislav Ivanoven_US
dc.language.isoenen_US
dc.peerreviewedYesen_US
dc.publicationstatusPublisheden_US
dc.publisherTrans Tech Publications Ltden_US
dc.relation.ispartofJournal of Metastable and Nanocrystalline Materialsen_US
dc.relation.publicationcategoryKonferans Öğesi - Uluslararası - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectAtomic mobilityen_US
dc.subjectBrownian motionen_US
dc.subjectDiffusion in liquidsen_US
dc.subjectGlass-transitionen_US
dc.subjectStokes-Einstein relationen_US
dc.subjectSupercooled liquidsen_US
dc.subjectViscosityen_US
dc.subjectVogel-Tamman-Fulcher lawen_US
dc.subjectGlass-Transitionen_US
dc.subjectDiffusionen_US
dc.titleBreakdown of the Stokes-Einstein relation in supercooled liquidsen_US
dc.typeConference Objecten_US
dspace.entity.typePublication

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