Breakdown of the Stokes-Einstein relation in supercooled liquids
dc.contributor.author | Dimitrov, Ventzislav Ivanov | en_US |
dc.date.accessioned | 2015-07-14T23:48:27Z | |
dc.date.available | 2015-07-14T23:48:27Z | |
dc.date.issued | 2004 | |
dc.department | Işık Üniversitesi, Fen Edebiyat Fakültesi, Fizik Bölümü | en_US |
dc.department | Işık University, Faculty of Arts and Sciences, Department of Physics | en_US |
dc.description.abstract | Breakdown of the Einstein-Stokes relation in undercooled liquids is one of the unsolved problems in the theory of liquids. The self-diffusion coefficient follows the temperature dependence of the Einstein-Stokes equation D = kT / 6pietar at high temperatures but only down to approximately 1.2T(g) (T-g - glass-temperature). Below 1.2T(g) the temperature behavior of the diffusion coefficient is weaker than 1/eta. In the present study we show that this is a consequence of increasing correlations in the Brownian motion of the constituting particles of the liquid. We derive a relation, which includes the Einstein-Stokes equation as a limiting case for high temperatures. | en_US |
dc.description.version | Publisher's Version | en_US |
dc.identifier.citation | Dimitrov, V. I. (2004). Breakdown of the Stokes-Einstein relation in supercooled liquids. Journal of Metastable and Nanocrystalline Materials, 20-21, 541-545. doi:10.4028/www.scientific.net/JMNM.20-21.541 | en_US |
dc.identifier.doi | 10.4028/www.scientific.net/JMNM.20-21.541 | |
dc.identifier.endpage | 545 | |
dc.identifier.isbn | 087849944X | |
dc.identifier.issn | 1422-6375 | |
dc.identifier.scopus | 2-s2.0-8644227798 | |
dc.identifier.scopusquality | N/A | |
dc.identifier.startpage | 541 | |
dc.identifier.uri | https://hdl.handle.net/11729/666 | |
dc.identifier.uri | http://dx.doi.org/10.4028/www.scientific.net/JMNM.20-21.541 | |
dc.identifier.volume | 20-21 | |
dc.identifier.wos | WOS:000223641200084 | |
dc.identifier.wosquality | N/A | |
dc.indekslendigikaynak | Web of Science | en_US |
dc.indekslendigikaynak | Scopus | en_US |
dc.indekslendigikaynak | Conference Proceedings Citation Index – Science (CPCI-S) | en_US |
dc.institutionauthor | Dimitrov, Ventzislav Ivanov | en_US |
dc.language.iso | en | en_US |
dc.peerreviewed | Yes | en_US |
dc.publicationstatus | Published | en_US |
dc.publisher | Trans Tech Publications Ltd | en_US |
dc.relation.ispartof | Journal of Metastable and Nanocrystalline Materials | en_US |
dc.relation.publicationcategory | Konferans Öğesi - Uluslararası - Kurum Öğretim Elemanı | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | Atomic mobility | en_US |
dc.subject | Brownian motion | en_US |
dc.subject | Diffusion in liquids | en_US |
dc.subject | Glass-transition | en_US |
dc.subject | Stokes-Einstein relation | en_US |
dc.subject | Supercooled liquids | en_US |
dc.subject | Viscosity | en_US |
dc.subject | Vogel-Tamman-Fulcher law | en_US |
dc.subject | Glass-Transition | en_US |
dc.subject | Diffusion | en_US |
dc.title | Breakdown of the Stokes-Einstein relation in supercooled liquids | en_US |
dc.type | Conference Object | en_US |
dspace.entity.type | Publication |
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